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Update:
I fucked up trying to paint the glasses and resorted to spray paint to cover up the whole head. It failed
Made more heads, each had a fuck up until I decided to make a new mold and fix the original of imperfections with more sculpting putty. New mold was ok, better that previous but still has a lot of imperfections to sand. Gonna get a spray gun since spray paint is a no go. Casts are now coming out clearer, possibly an imbalance between parts A & B when casting.