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Ok, so, I got my first batch of IV'd Zigz out. They all have max attack, thanks to that Smeargle, but 2 of them also have max speed thanks to the fact that the female I bred to have Adamant had the luck of being Max Speed.
So, now I have a female with max Attack and Speed. Should I exchange the female currently in the day care for her and then put the Defense power item on the Smeargle?