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You can easily grow a very toxic mold that can kill you in less than 15 minutes from peanut butter as a substrate.
You can catch a black widow and force her to bite you.
You can use a kerosene or butane heater/car-gas-tube/gasoline candle to produce carbon monoxide and then kill you by hypoxia.
You can buy a Helium tank or 100 balloons with Helium and put it in a small closed room with you inside.
You can take 60 analgesics or take a codeine overdose.