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It's Sakuya Izayoi (not her real name) from Touhou (first appearance in Touhou 6 as Stage 5 Boss) and she is the chief maid of the Scarlet Devil Mansion in Gensokyo. It's located in the near of the Misty Lake, where Cirno also somewhere in an igloo lives.
She is skilled in throwing knives and can use time manipulation with a magical stopwatch.
In this image she had a fight with someone and adjust her gloves, but at the very moment Aya Shameimaru made a sneaky wind attack to lift her skirt for a panty shot photo for her collection.
