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I use outer heavier wool socks, and inner thinner cotton ones
But it really depends on your feet an boots
Wear your boots and socks around a bit and see how you like them
But I recommend having at least 2 pairs of whatever you are bringing
Wash 1 pair every day and have them drying on the outside of your pack
When you walk a lot it compresses the fibers and the socks lose their loft leading to blisters
Fluffy socks will make sweet love to your feet for miles