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Situations like that are golden for meeting a girl.
If you're in a bar, you're just a creepy ugly guy. Trying going up to a girl and you will be rejected.
But, you're both hiking. Before either of you even speak a word you already have common interests that you both know about. You also therefore have something to talk about to start the conversation. There's also probably not many other guys around to show off how ugly you really are.
THEN you are given then GOLDEN opportunity, you run into her again. All you have to do is say lightheartedly "we keep running into each other, I could get used to this"
If her response is positive, maybe you're in. Say "hey maybe I could give you my number/facebook/snapchat/Insta (whatever the kids use nowadays) so we could hoke together sometime.
If she says she has a boyfriend, say "ah no problem, he's a lucky guy!" And part ways. No harm no foul. You're not creepy and she can carry on with her day.
The worst she can do is say no. You just respond "ok it's all good" and move on.
BUT of she responds positive, you're in. You already have a first date idea, you already have something to discuss later, ect ect.
What the fuck bro? You miss 100% of the shots you do... whatever. Just get your shit together or go back to /r9k/.