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Looks like your socks are the wrong material or not T H I C C enough. I trust you already have suitable hiking boots. Get wool socks that look like they're straight out of a skiing vacation advert. I've just done several days of hiking last week and I could feel some sore spots on my feet at the end of the day, but not a single blister, whereas I've gotten blisters in the past solely from walking to school with shitty socks and shitty shoes for 45 minutes.