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I'VE DONE IT... partially. Peg hole didn't come in right, and I tried a mask of water, which didn't turn out right either. This can kind of sit on a face loosely because of the grooves though.
BUT
I'm seeing now, if I pour resin into the peg/mask connector sections allow those to cure first, and pour the resin into the mold's "bowl" section, then press the other end in, I should be able to get decent results without needing a pressure or vacuum chamber.
BUT it probably won't work so well with the transparent resin. To get that to be flawless, it'd really require the chambers....