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I know it should be Mafex. By all means its the best on a technical level. But having collected and owned pretty much ever major 6'' classic style Wolverine, I still go back to the ToyBiz ML Series 6 Wolvereine. Yes, I know, weird joints, mushy sculpt, whatever. It just captures my ideal of what Wolverine looks like so well.
Runner up for me in terms of sculpt would weirdly be the X-men Classics Wolverine, unfortunately its hurt by its gimmick.