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Going into pure fantasy territory here, but since Jada has said they're open to doing other Capcom IPs, I imagine if they took on Darkstalkers they'd do it in a similar 3 figure per wave format with a similar mix of more popular and less popular characters per wave. Since the girls tend to be the more well known, they could get spread out at 1 per wave, which would nicely fit into 6 waves to do the entire 18 character cast. The remaining 2 per wave could be divided between some of the more popular/well-known guys and the more obscure ones. They could also try to spread the bigger guys out for pricing/material cost reasons. So here's my idea:
Wave 1:
Morrigan, Demitri, Victor
Wave 2:
Felicia, Talbain, Sasquatch
Wave 3:
Hsien-Ko, Lord Raptor, Bishamon
Wave 4:
Q-Bee, Anakaris, Donovan
Wave 5:
Lilith, Rikuo, Huitzil
Wave 6:
B.B. Hood, Jedah, Pyron