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How I (male) rank the PoP ladies:
S: She-Ra and Adora, Frosta, Octavia, Entrapta
She-Ra is the main character and a classic design, her Adora identity isn't as well-designed (a turtleneck under a leotard?) but still pretty good and necessary for Royal Family displays. Frosta is another great design and has an interesting niche in the setting. Octavia has the most playability and is a rare monster girl. And I rate Entrapta this high for her (reboot) personality.
A: Catra, Shadow Weaver, Sweet Bee. I don't love their toy designs (vintage toy Catra would be my favorite in this tier), but the first two are key characters and I want Sweet Bee for pic related.
Scorpia would be in this category if they give her pincers big enough to be an action feature (and preferably change her ugly Filmation head).
B: Mermista
C: toy Angella, toy Castaspella, Flutterina, Peekablue, Netossa, Spinarella.
F: Glimmer, Filmation Angella, Filmation Castaspella, Perfuma, Double Trouble, Star Sisters, Madame Razz.
OK, I know I should give Perfuma points for "Flowers for Hordak", but her design just doesn't say "dryad". Even with the flower theme to her dress, the green tights and flats or boots say "medieval woman who likes flowers" rather than "nature spirit".