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I live within a 20 min drive to Canada's Wonderland so I guess my town would be Nimbasa City.
For my first pokemon I have always really loved Trubbish. So I think I would try to catch him first on Route 16.
It would be perfect too, since trubbish stop smelling when they make friends with something. He can have his own little area of treasures he finds and eat as much trash as he wants to.