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Having beat the E4 rematches with both my not bred, not ev trained story team(they were around lv95 by the time I was done with Clovenix, so I easily got them to lv100) and my new perfectly bred and ev trained team(all around lv65), I have a few considerations:
1)HOLY SHIT, bringing the Amulet Coin to all the E4 fight will net you 272000$
2)A lv100 non ev trained story team can still take on any bullshit the game throws at the player, albeit it may need some strategy to do so
3)the level scaling and the opponents having perfect sets really make any form of snowballing impossible, so I never felt my new team was on a completely superior level than my old one despite the difference being huge