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I just like Garbodor because it reminds me of Yume 2kki.
Lucario, Zoroark, Gardevoir, Lycanroc, Weavile, Luxray and Mewtwo are more humanoid than average and thus attract furries.
Eevee has an incomplete branching evolution mechanic that has obvious fanart hooks.
Tsareena, Lurantis and Milotic have features that resemble secondary or tertiary female sexual characteristics and thus attract degenerates.
Bug-types...Some people like bugs.
I like Misdreavus, and I recognize that's because it looks like the face of an anime girl, but also because it has a recurring bowl shape in its head, eyes, mouth and necklace, and that recurring shape makes it aesthetically pleasing. Its evolution loses both and is ugly.