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Guys let's start a headcanon thread!
My headcanon is that houndoom is capapble of producing flame using calcium carbide; making a very hot acethylene flame. However sometimes it will also belch out some limewater (calcium hydroxide) left from the reaction which is a very basic solution and it is kinda hazardous, thats why the pain can last for a very long time if you are unaware what is it.