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Ok, I've got a sun team in the works.
Here is what I plan to have at the end.
Donphan @ Leftovers
Ability: Sturdy
EVs: 252 Atk / 252 HP / 4 SDef
Adamant Nature
- Earthquake
- Stealth Rock
- Rapid Spin
- Ice Shard
Charizard @ Charizardite Y
Ability: Blaze
EVs: 252 Spd / 252 SAtk / 4 HP
Timid Nature
- Flamethrower
- Air Slash
- Solar Beam
- Focus Blast
Volcarona @ Leftovers
Ability: Flame Body
EVs: 204 Def / 252 HP / 52 Spd
Bold Nature
- Bug Buzz
- Fiery Dance
- Quiver Dance
- Roost
Lilligant (F) @ Life Orb
Ability: Chlorophyll
EVs: 252 Spd / 252 SAtk / 4 SDef
Modest Nature
- Quiver Dance
- Sleep Powder
- Energy Ball
- Synthesis
Typhlosion @ Choice Scarf
Ability: Blaze
EVs: 252 Spd / 252 SAtk / 4 HP
Timid Nature
- Eruption
- SolarBeam
- Fire Blast
- Hidden Power [Rock]
And I'm at a toss up for the last slot between Espeon, for more stealth rock protection and some duel screens. Leafeon, to have someone who does physical damage and benefit from sun. or Ninetales, for extra sun.