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In terms of skill, wit, and perseverance, probably Wes. He single-handedly destroyed an evil team before the game even starts, and beats another evil team, led by some of the strongest trainers in the games, with only shitmons at his disposal. He can operate explosives, ride a hoverbike, and steal other people's Pokémon.
Else either Cynthia, Red, or Eathen (if beating Red is canon).
