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The female player character automatically gets plenty of porn, but gym leaders and the rest are a bit trickier. Misty managed to get an early surge for obvious reasons. After that, it was only until Cynthia in DPP where we got another non-MC character popular with fanartists. Skyla and Elesa both were popular from the start after Cynthia. I remember seeing plenty of fanart of these 2 early into BW1's release. XY's failed to produce such a character sadly with Diantha and Korrina not being as popular.