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I've bred a few. Namely Nincada, Litwick, Clauncher (before I knew about chain fishing), Honedge, Noibat, two Fennekin (one right after the other, somehow), Phantump, and Chespin.
I've found a few Eevees, an Audino, and two Teddiursa and Aipom in Friend Safaris.
Chain fished up a Luvdisc and Magikarp.
Random encounters have been Pancham, Marill, Zigzagoon, Ponyta, Starly, Shinx, and Abra.
Only two have escaped so far, Abra and Electrode. I really thought that my Haunter would get the first move, but that was not the case.
Since then I've traded around on the GTS to completely fill out shiny Kalos Pokemon and all the Legendaries I can in the Bank as a sort of living shinydex. Really want to get a Steelix for when ORAS comes out because, dayum.