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Cryogonal because of its shape and its French name Hexagel, and because finally France is often nicknamed "The Hexagon".
Mr Mime because good ol' Marcel Marceau.
Roserade because of the parfum industry and cities like Grasse.
Furfrou because of the poodles.
Politoed because of frog legs.
Combusken because of the Gallic Rooster.
I could've also included Solrock (Louis XIV), Braviary (Napoléon Bonaparte) or Gardevoir (Marianne).