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Well, I couldn't pick just one now, could I?
>Blastoise for guns.
His loyal tank partner.
>Luxray for his love of ocelots.
Tied with Persian but Archer prefers exotic, and a lightning lynx is closer to an exotic ocelot than a housecat.
>Arcanine for his love of dogs and other badass animals.
Also it was the closest any pokemon looks to a tiger, and Archer has to have a tiger. Plus fire is neat.
>Spinda for his drinking buddy
Archer needs a wee baby Seamus in his life to go drinking with him and cause mischief, and Spinda fits to a tee.
>Crobat because... it's fucking awesome.
>Garchomp because oh my god, a freaking jet shark!
And finally, his shoulder mon who isn't part of his actual team because he cares too much for the little guy:
>Cubone. Because mommy issues.