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Gallade in SV was one I enjoyed using a lot
>can get it as a ralts at the start of the game or as kirlia on titan orthworm's route
>open world so you can get a dawn stone right away
>gets sacred sword, night slash, leaf blade and aqua cutter via relearner
>sharpness + 125 attack shreds everything
>learns hypnosis and false swipe if you want something for captures
Only downside is that it doesn't get psycho cut until 40 something but you can find zen headbutt as a TM if you really want psychic coverage
