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I love using this little thing. It can be extremely annoying and a stop to volt switchers (!!) while halving a potential threat/wall's HP.
My Pachirisu set:
Pachirisu@Air Balloon
252 HP, 252 Speed, 4 Special Def
Jolly Nature
Super Fang
Nuzzle
Toxic
Volt Switch/Charm/Sweet Kiss (if you want to be cheeky)
also it's adorable. I recently bred a 6IV one, but unfortunately has Run Away..