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When the Nidoking falls, Cain will send out his Samurott, which is obviously a bad choice.
He loves to spam Discharge. Not only will Discharge hit both targets with boosted power, he'll usually have a volt Absorb Mon out, or pic related to get boosts. Discharge will also change the field into a factory, field, which guarantees a boost of 1.2 to electric attacks, and vice versa.
The field change triggers every time Discharge successfully does damage, not when it's used.