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Shiny Skrelp from an afternoon of chain fishing in Y. Felt hollow, immediately pawned it off on GTS for a Xerneas because the games were still fresh.
Then a Shiny Gastly while breeding. Wasn't even Masuda, just trying to get my pentaperfect Gengar, and the first pentaperfect egg was a shiny. Of course this was right on the cusp of Sun and Moon coming out, pentagon pokemon becoming worthless, and Gengar getting knocked down a few pegs.
Then a Shiny Snorunt while masuda breeding. But I was breeding it specifically to trade for something else. I was trying to get a female and got a male, so this is just sitting in my box as a failure.
Then a Shiny Snorunt that was female which I traded for a Diancie.
...Then a Shiny Snorunt in the wild during my first Moon playthrough, female, and timid. Wasn't even SOS chaining.