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Here are a set of non legendary mono psychic Pokemon (missing Wobbuffet, Espeon, Chimecho and Unown)
Hypno has a nice Sp. Def but its offensive stats and speed are too low to use it as anything other than a special wall (with poor support moves, at least in Gen VI)
Grumpig has slightly worse bulk but better speed and a usable special attack. Excellent coverage moves too, most notably Power Gem.
Musharna is slow but has the best bulk of the lot, and a plethora of support options (including Healing Wish, Baton Pass and Helping Hand)
Gothitelle owes a lot to its Ability, but it's stats are nothing to sneeze at. Low speed can be problematic. Atrocious offensive movepool.
Beeheeyem is powerful and enjoys analytic, but is too frail to abuse it for very long. Outclassed defensively by Musharna and Gothitelle and offensively by Reuniclus.
Reuniclus makes excellent use of Magic Guard and a Life Orb, and has Recover. Really solid Trick Room attacker.
Female Meowstic is bad. Male Meowstic is a good Prankster.
Alakazam is fast, hits hard and has ok coverage, but is physically frail. Magic Guard Life Orb is fun here too.
