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The only one shiny i've ever encountered in the safari zone was a Seaking in fire red... I threw a safari ball, 3 shakes and... nope it fled.
But i've catched every shiny I found since, luckily.
The last week I started a new game in my Heart gold, about 16 hours of game later in Ilex forest —Motherfucking shiny metapod! Almost killed it with a critical hit and I threw it about 8 pokeballs, finally got it with a great ball.
Two days later in ruins of alph-- wait what? that fucker is shiny? Yeah a shiny Natu! Fast ball click at the fist time.
I named it Dicks and Hooters respectively