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Here's a concept for a poison trainer nurse named Venera.
Her team all has some sort of role within her job.
>Galarian Slowking
The brains, gives off mad scientist vibes which fits well as the ace. He brews potions so he's the drug maker
>Salazzle
Femme fatale style mon and obvious second choice. pheromones are used in some medicines (or to lure in unwilling subjects)
>Vileplume
Catch-all for plant materials and the most visually fitting of the grass/poisons
>Swalot
The waste disposal. Eats all the stuff that doesn't work. Big purple trash can.
>Skuntank
The knockout spray. Also reflects the fact that hospitals smell like ass
>Okidogi
The ever reliable animal test subject. He's even got a Bane venom chain thing going on
Basically the idea for her character is that she leverages her knowledge of toxins and what makes them progress from her medical work to strike at your weaknesses more effectively. Venoshock fits the MO so it's the TM. A lot of the inspiration came from Klara so she'd be a similar flavor of petty bitch, just with more actual competence to back it up.
The gym would be a hospital obviously, perhaps the backrooms of the pokemon center itself. Gimmick is that you get sprayed with something new in each room and have to figure out how to treat it with the materials available. She'll use the data to adjust her strategy for dealing with you.