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Psychic is supernatural stuff pertaining to the mind. The Lake trio represents aspects of the human mind. Metagross and Alakazam have superintelligence. Gardevoir has an emotional connection to its trainer. Starmie is telepathically communicating to something in space. Espurr has a bunch of energy stored in its brain. Mr. Mime plays tricks on people's minds. Gothitelle has clairvoyance. Beheeyem alters people's memories. And so on.
I guess Lunatone/Solrock, Baltoy, and Bronzor are animated by "psychic energies." Celebi should probably be Fairy, but it won't be.
Fairies are a more vague "cute and magical" kind of supernatural, with inconsistencies like Dragons.
