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You can go physically defensive for a Talonflame check, ect:
Rotom-W @ Leftovers / Chesto Berry
Bold
252 HP / 252 Def / 4 SpA
Volt Switch
Hydro Pump
WoW
Pain Split / Rest
I also like the bulky Specs set:
Rotom-W @ Choice Specs
Modest
252 HP / 4 Def / 252 SpA
Volt Switch
Hydro Pump
WoW / Thunder
Trick