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The Lucario movie (M8) is great. If you don't cry at the end, you have no soul. Darkrai movie (M10) had top-tier music, but I don't remember the plot. Probably gonna rewatch it soon while breeding maison pokes or something.
Lati@s movie (M5) is one of my current favorites - a great soundtrack, interesting setting (Pokemon Venice? Seems good), and Latias being the most adorable little shit.
Pretty much any of those three is worth a watch. The Deoxys movie (M7) is shit, skip it. You'd think a movie with Deoxys vs. Rayquaza would be awesome, but no. Celebi movie (M4) is the Pokemon version of Fern Gully. Decent, but I'd rather watch Fern Gully.
The other movies were not memorable, and I haven't seen the most recent few.