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>Normal/Poison
A lizard with a tail that looks like a snake to scare away predators, though it will pop off and wiggle to keep other predators occupied.
>Normal/Ice
Husky with snow leopard spots.
>Poison/Fairy or Fairy/Dark
Corrupt fairy that looks like a little witch with clothing made from dead plants. Give it an ability that allows it to boost something when around Ghost, Poison, and/or Grass types.
>Bug/Dragon
It'd be too obvious that make a literal dragonfly, so how about a serpentine centipede, a mantid wyvern, or a lizard that carries the shell of a beetle around and fuses with it (think cubone to marowak) when it evolves.
>Bug/Psychic
A giraffe beetle with a radio tower looking head that broadcasts it's psychic powers.