After their Gym battles with Ash (in which he more or less beats them despite it not being a proper battle), all I remember them doing is bombing or failing all the rest of their battles in Kanto, and Misty only ever winning when Psyduck got a headache.

Then in Johto, again, I barely remember Brock battling at all, and the only Misty battles were a few with Poliwhirl/Corsola at the tail-end of the saga. Are there any really good Misty/Brock battles to watch barring nostalgia?