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First one I ever saw was a shiny Whismur back in Sapphire; didn't know it was a shiny then, and I was obsessed with glitches in games at the time so assumed he was one. His name was Green Bean. I also saw a Shiny Hariyama during the same playthrough, but he used whirlwind during battle.
I ended up deleting that save file, because I wanted to replay Sapphire; but being a dumb kid I didn't transfer over any of my Pokemon. I even had an event Mew on it! ;_; Though, to be fair, I got the same event Mew on 4 other games at the time, and cloned it to heck in Emerald, so I have a few dozen of him throughtout all the generations. But Green Bean is still gone for good..