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For reference, S tier are my absolute favorites and A tier is ideal/good. B tier is what I consider boring/disappointing, but not unacceptable. C tier I consider bad ideas/badly designed, while D tier is reserved specifically for Mega-Salamence.
Mega-Salamence completely ruins what I consider to be Pokemon's take on a classic dragon design. Just thinking about him moving around in a realistic way after he mega-evolves is hard to think about, on top of the shape of his wings generally just being unpleasant to look at. Honestly, he just doesn't look capable of flight at all, and it's harder to handwave and say it's levitating than an inorganic Pokemon like Glalie or Weezing.