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No, max affection isn't really "max", it's merely the plateau for which people who have a purely platonic relationship with their pokémon can reach. The bond between a pokémon and human in a committed loving relationship with each other is far greater and more terrible than you could possibly imagine. Where do you think the knowledge Gardevoir being able to pull black holes out to save their trainers came from? She did everything in her power to save her lover's life and got immortalised in the pokédex for it.