>>48947629well technically in frlg he uses gen 1 pokemon despite it being gen 3, he also uses pokemon introduced in other gens during his rematches as well.
Alder is the only champion that fits this criteria since he only appears in gen 5 (in the main series) and doesn't use any non gen 5 pokemon in any of his alternate teams
Also the player character in alola/galar could fit the criteria as well. The player characters in gen 6 and below probably wouldn't count when you rematch the 'campion' they still retain their title.