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Probably not. Rarity would focus too much on beauty and fashion, Flutter wouldn't like fighting, AJ would just try and beat everyone with brute force, Rainbow would screw herself over trying to pull off some high-risk high-reward play, Twilight would have some billion IQ team that accounts for every possibility but would crack under the pressure when things aren't going her way, and who really knows about Pinkie?
They do line up pretty well as stat aces though.
HP: Flutter
Atk: Pinkie
Def: AJ
Spa: Twilight
Spd: Rarity
Spe: RD
