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I still wouldn't watch because watching other people have fun is a waste of time, but I'd put any of them on in the background while I'm shitposting. Mostly men because female anime characters with strong enough charisma to carry a stream without being obnoxious, noisy or otherwise off-putting are in the minority. Also, yes, /m/ is my kamioshi board and has been forever.
Japanese:
Axel Almer (Super Robot Taisen)
Ryusei Date (Super Robot Taisen)
Masaki Andoh/Gridman (Super Robot Taisen/SSSS Gridman)
Shu Shirakawa (Super Robot Taisen)
Lamia Loveless (Super Robot Taisen)
Gintoki/Edge (Gintama/Super Robot Taisen)
Kazuma the Treasoner (Scryed)
Sandman (Gravion)
Carrera (Viper GTS)
Van (Gun x Sword)
Jiro Yamada (Nadesico)
G-Wrench (Gear Gadget Generators)
Roger Smith (Big O)
Subaru Nakajima (Nanoha)
Anti (SSSS Gridman)
Chang Wufei (Gundam Wing)
English:
Coop (Megas XLR)