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amesame - main couple #1. First meet after the disturbance created by Ame arriving in the past woke Gura from her post Atlantis coma/hibernation. Split up in vol 24 Echoes of Atlantis but get back together later during the Avocado Tree arc
takamori - main couple #2. Meet shortly after Ame, Gura, and Ina meet. It is later revealed in the special issue Extinction War Eternal that Mori has been the reaper meeting Kiara at the River Styx during all of her revivals. The damage to Kiara's memories during her fights against all the phoenixes led to her forgetting. As Kiara's supply of phoenix down dwindles and her memory grows worse, mori knows soon there'll be one day she won't be able to turn her back from the banks of the river.
sanina - gets together after the council awakening art. sana's destruction leads to ina overusing her powers trying to bring her back, leading to ina [corrupted form]
baerys - gets together during the death cult plague arc. hajimete no chu unlocks irys's seraphim of hope form
faumeinii - Fledgling guardian of civilization becomes attached to them after the council awakening arc. Wavers during the sands of time arc and the devastation silent spring arcs. Mumei is forced to make a choice in the 4044 AD OVA.
t. the voices in my head are up to date on the latest issue of MYTHJump