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In the second season of Cardcaptor Sakura, the Clow Cards lost their effectiveness primarily due to the introduction of the new antagonist, Eriol Hiiragizawa. Eriol, who is revealed to be the reincarnation of Clow Reed (the creator of the Clow Cards), begins testing Sakura's magical abilities and powers in order to prepare her for a new set of cards called the Sakura Cards.
Eriol's presence and actions gradually weaken the Clow Cards that Sakura already possesses. This weakening is symbolic of Sakura's transition from being the master of the Clow Cards to becoming the master of her own power and destiny, as represented by the transformation of the Clow Cards into the Sakura Cards.
Furthermore, Eriol's role is pivotal in Sakura's growth as a magician. His influence not only impacts the Clow Cards but also serves to challenge and strengthen Sakura's magical abilities throughout the series. Thus, the Clow Cards' decreasing effectiveness in season 2 is part of the overarching narrative that drives Sakura's progression as a magical girl.