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As a Nina historian, I can enlighten as to several reasons
>strong kayfabe that makes her look offputting next to her coworkers
Nijisanji tends to have a very casual and light kayfabe. That said, Pomu has a strong kayfabe and also fits in, so it comes down to Nina just not doing it properly.
>mommy archetype doesn't suit her
The most annoying part about her pushing the honey shit is she's in like, her late twenties. Actual cakes like Shuba and Korone give off very distinct calm and mature vibes, that the young can't really emulate
>unaware as to how she comes off to people
She often says shit that can be construed as offensive, and her collab partner is left holding the bag, trying to figure out if she's actually autistic, or just playing dumb
>has a tendency to victimize herself
When she called the other members of Ethyria out for cutting her off. Sure, she might have been hurt, but it's entirely unprofessional, and extrememly adversarial to her closest colleagues
>collab with males
She leeched off them pretty blatantly. Also had some sort of off-collab where she slept in the same house as them? Pretty easy way to kill the unicorns, which is a shame, because unicorns would have been a pretty good audience for her.
Despite it all, she's a decent entertainer solo but it's only herself that's holding her back.