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This is a frightfully difficult question. I can name my top movies on one hand, and even my favorite (blade runner).
Yet books are so much more difficult. I can think so many books I consider fantastic. Pratchett, Orwell, Asimov, Huxley, Bradbury, Clarke, Aurelius, Aquinas, it never ends.
I suppose if I had to pick, it would be Ecclesiastes. It is beyond reproach in philosophy, religion, composition and story.