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talk to her or break up with her. jealous snooping and mindgames have yet to save a single relationship.
if you really can't handle not knowing what she does on skype, be honest about your insecurities and ask her for access.
seriously, what's the best outcome you expect here? if you find dirt, you have to break up with her because she violated your trust. if you don't find anything and she's a saint, *you*re* now at risk of her breaking up, because you majorly violated her trust by spying on her. are you really at a point in your relationship where fucking your girlfriend over and hoping she'll never find out is the *best* outcome imaginable? jesus, take a step back and reconsider.
also: being super jealous about a skype username and posting said username on 4chan with the small hint your girlfriend is involved is usually not the smartest. i can only image how many messages about an asshat of a jealous boyfriend Jak.adit has already received.