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Difficulty creating a PNGs

No.1546084 View ViewReplyOriginalReport
Until now, it has been quite easy to create PNGs of drawings for my RPG tokens, especially in Photopea, which has an automatic Magic Wand feature, so I just touch them up afterwards.
However, I am having difficulties with this particular artwork (https://files.catbox.moe/fn016v.jpg), and I have no idea why. So, I realize that I need to learn more about how to create PNGs in general.
What are the different approaches to making PNGs? If possible, links to tutorials/blogs would be very helpful.