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I tried to get into the Index/Railgun series, and I was kind of expecting that Misaka and Touma would be the two main characters, kind of disapointed its not the case. Index is about Touma protecting some loli church nun and Railgun is some kind of yuri adventures with Misaka and Kuroki.
>note: I've only watched like 7 episodes of Index and 2 episodes of Railgun