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I thought Chuunibiyou was very good in that sense, although I haven't watched the last episode.
My favorite romance anime is that in which the characters are either good friends and fall in love, or, even better, like in ToraDora, where they THINK they "love" someone else only to find out what they need is right under their noses.
Can't say I've watched anything other than ToraDora, Kachou wa maid and Chuunibiyou though. Inu X Boku looks to be "somewhat maybe" similar.
Anyway, I don't recommend watching ToraDora or the like as I did, right after being rejected back in high school. Although at the end it did make me realize it was stupid pouting over some chick because she's pretty.
