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Regardless of how naughty or tomboyish she might look, Misao is actually the most innocent, open, well-meaning, radiant and positive character in the series. Unlike all the other characters, she never even once hides anything or pretends to be something she's not, not even as a joke. She does not know how to bear grudges or to be truly upset or angry at somebody. More importantly, she does not have the capability to be anything other than herself.
All of which makes her awesome.