>>112500OP i got blisters like this once from hiking about 7 miles in wet boots/socks. it sort of hurt pretty badly.
now those look like some nice work boot style boots you have there but. they are not designed for hiking. not trying to be a jerk but in my opinion those are the wrong boots to be hiking in.
dedicated, specifically designed "hiking boots" are your best bet, granted they too must be broken in to function well.
i know its just my opinion. but i feel pretty strongly about it, at least for myself. ill never do any hiking in a boot like those work boots unless theres no other option