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So based on the blank spaces in the sprites rips, and the short trailer also seen in the demo, it's safe to assume the trials we're getting include
Captains
>Ilima, Normal - Totem Gumshoos (Sun) or Raticate (Moon)
>Mallow, Grass - Totem Lurantis
>Kiawe, Fire - Totem Salandit's evo
>Lana, Water - Totem Wishiwashi
>Sophocles, Electric - Totem Vikavolt
>Waifu showed in the demo, Ghost - Totem Mimikyu (it has two blank spaces, so the stat increase probably varies depending on the version)
>???, Dragon - Totem Kommo-o
Kahunas
>Hala, Fighting
>Olivia, Rock
>Eyebrows lady, Ground
>Pelliper dude, Flying